Do you mean a VIP version of these staff? In that case, it's kind of weird. Basically you'd have to have separate groups (such as administrator_vip). If I had to choose, they'd go directly above their regular counterparts (administrator < administrator_vip < administrator_vip+ < headadmin < ...).
Edit: But then you'd have to change inheritances and can_targets and it becomes complicated if you want VIP groups to have certain positions that staff don't.
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You have to do literally what he said.
Start from the bottom and work your way up.
(> = inherits from) user > vip > vip+ > tmod > tmodvip > tmodvip+ > etc..
In your inheritance chain you'll want it so tmod can target everyone below moderator. So all
three tmod ranks should have can_target
!%moderator. Next level up you want moderator > moderatorvip > moderatorvip+. All
three should have can_target
!%administrator.
Personally, I disagree with the idea of staff having VIP status on a server but if you want it so they inherit each other and have the same targets, then it's a long and painful process. If you do it all correctly, they SHOULD be in order in the ULX GUI ranks menu.
If you need further help, feel free to contact me.